Publications

2024

Ammonia activation using a heteroleptic stannylene and lithium stannylenoid formation facilitated by hemilabile iminophosphorane-based ligands
Krengel, D. M. J.; Graw, N.; Herbst-Irmer, R.; Stalke, D.; Townrow, O. P. E.; Fischer, M.
2024. Inorganic Chemistry Frontiers, 11 (24), 8649–8659. doi:10.1039/D4QI02202E
Selectivity control in the reactivity of dipyrromethene gallium(I) complexes
Richter, T.; Thum, S.; Townrow, O. P. E.; Langer, J.; Wiesinger, M.; Harder, S.
2024. Journal of Organometallic Chemistry, 1021, Art.-Nr.: 123356. doi:10.1016/j.jorganchem.2024.123356
Dipyrromethene as a Ligand for the Stabilization of Low-Valent Gallium Complexes
Richter, T.; Thum, S.; Vilpas, T.; Townrow, O. P. E.; Klerner, L.; Langer, J.; Harder, S.
2024. Organometallics, 43 (12), 1377–1385. doi:10.1021/acs.organomet.4c00164
Synthesis, Structure, and Reactivity of a Superbulky low‐Valent β‐diketiminate Ga(I) Complex
Richter, T.; Thum, S.; Townrow, O. P. E.; Wiesinger, M.; Langer, J.; Harder, S.
2024. Zeitschrift für anorganische und allgemeine Chemie, 650 (11-12), Art.-Nr.: 202400044. doi:10.1002/zaac.202400044
En Route to a Molecular Terminal Tin Oxide
Kreßner, L.; Duvinage, D.; Puylaert, P.; Graw, N.; Herbst-Irmer, R.; Stalke, D.; Townrow, O. P. E.; Fischer, M.
2024. Inorganic Chemistry, 63 (16), 7455–7463. doi:10.1021/acs.inorgchem.4c00598
Metal Vapour Synthesis of an Organometallic Barium(0) Synthon
Townrow, O. P. E.; Färber, C.; Zenneck, U.; Harder, S.
2024. Angewandte Chemie International Edition, 63 (5), Art.-Nr.: 202318428. doi:10.1002/anie.202318428
Controlled cluster expansion at a Zintl cluster surface
Townrow, O. P. E.; Weller, A. S.; Goicoechea, J. M.
2024. Angewandte Chemie International Edition, 63 (3), Art.-Nr.: 202316120. doi:10.1002/anie.202316120

2022

Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand
Tsoureas, N.; Rajeshkumar, T.; Townrow, O. P. E.; Maron, L.; Layfield, R. A.
2022. Inorganic Chemistry, 61 (50), 20629–20635. doi:10.1021/acs.inorgchem.2c03534
Zintl cluster supported low coordinate Rh( i ) centers for catalytic H/D exchange between H and D
Townrow, O. P. E.; Duckett, S. B.; Weller, A. S.; Goicoechea, J. M.
2022. Chemical Science, 13 (25), 7626–7633. doi:10.1039/D2SC02552C

2021

Thermoneutral N−H Bond Activation of Ammonia by a Geometrically Constrained Phosphine
Abbenseth, J.; Townrow, O. P. E.; Goicoechea, J. M.
2021. Angewandte Chemie International Edition, 60 (44), 23625–23629. doi:10.1002/anie.202111017
Cluster expansion and vertex substitution pathways in nickel germanide Zintl clusters
Townrow, O. P. E.; Weller, A. S.; Goicoechea, J. M.
2021. Chemical Communications, 57 (58), 7132–7135. doi:10.1039/D1CC02912F

2020

A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
Townrow, O. P. E.; Chung, C.; Macgregor, S. A.; Weller, A. S.; Goicoechea, J. M.
2020. Journal of the American Chemical Society, 142 (43), 18330–18335. doi:10.1021/jacs.0c09742

2017

Stepwise Investigation of the Influences of Steric Groups versus Counterions To Target Cu/Dy Complexes
Kühne, I. A.; Griffiths, K.; Hutchings, A.-J.; Townrow, O. P. E.; Eichhöfer, A.; Anson, C. E.; Kostakis, G. E.; Powell, A. K.
2017. Crystal growth & design, 17 (10), 5178–5190. doi:10.1021/acs.cgd.7b00648
3d/4f Coordination Clusters as Cooperative Catalysts for Highly Diastereoselective Michael Addition Reactions
Griffiths, K.; Tsipis, A. C.; Kumar, P.; Townrow, O. P. E.; Abdul-Sada, A.; Akien, G. R.; Baldansuren, A.; Spivey, A. C.; Kostakis, G. E.
2017. Inorganic Chemistry, 56 (16), 9563–9573. doi:10.1021/acs.inorgchem.7b01011